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Silver orthophosphate, Ag3PO4

With solutions of normal or secondary sodium orthophosphate Silver nitrate gives a yellow precipitate of silver orthophosphate, Ag3PO4, containing Silver nitrate which cannot be removed by washing. Secondary silver orthophosphate, Ag2HPO4, is obtained in white crystals from the solution of the normal orthophosphate in aqueous phosphoric acid. At 170° C. it changes to the pyrophosphate.
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